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Ordinary polystyrene resin is an amorphous polymer, the side group of the polystyrene macromolecular chain is the benzene ring, and the random arrangement of the large volume side group is the benzene ring determines the physical and chemical properties of polystyrene, such as high transparency. High stiffness. High glass transition temperature, brittleness, etc.
Expandable polystyrene is made of a physical foaming agent impregnated with low boiling point in ordinary polystyrene, which is heated and foamed during processing, and is specially used to make foam products. High-impact polystyrene is a copolymer of styrene and butadiene, and butadiene is the dispersed phase, which improves the impact strength of the material, but the product is opaque. Conventional polystyrene is the same structure, produced by metallocene catalyst, and the new variety of polystyrene developed has good performance and belongs to engineering plastics.
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1.Selection of emulsifiers. This is a key factor in the stability of the polymerization reaction, as improper selection of emulsifiers can lead to gels or delamination after placement. The amount of emulsifier used is also critical. It can affect the stability and performance of the emulsion.
2.In terms of process, the main aspects are the sequence and speed of the compound, as well as the temperature control of the different reaction stages.
3.The speed of stirring will also have an effect.
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Emulsifiers are critical, and the pre-emulsification process is also required; Attention should also be paid to the mixing speed and the shape of the mixing paddle. Also, the solid content should not be too high, it is easy to gel.
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Answer: Acrylic emulsions need to be fully polymerized.
Explanation: Acrylic emulsion is an emulsion liquid containing acrylic monomers, emulsifiers, water, etc., which is commonly used in coatings, adhesives, and other fields. Before use, the acrylic emulsion needs to be polymerized to polymerize the monomer molecules into macromolecules, so that they have certain curing and mechanical properties.
If it is not fully polymerized, it will lead to problems such as unsmooth coating surface and poor adhesion, which will affect product quality and service life.
Expansion: The polymerization process of acrylic emulsion generally requires the addition of additives such as initiators and stabilizers to control the polymerization rate and stabilize the properties of the liquid. Common initiators are ammonium persulfate, potassium persulfate, etc., and stabilizers are sodium dodecylbenzene sulfonate, sodium dodecyl sulfate, etc.
In the polymerization process, it is necessary to pay attention to the control of temperature, pH value and other conditions to ensure the smooth progress of the polymerization reaction.
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For acrylic emulsions, complete polymerization of the acrylic monomer is often required for optimal performance and stability. This process can be facilitated by the addition of appropriate initiators, heating, stirring, controlling the pH of the solution, etc. Complete polymerization ensures that the acrylic monomer content in the emulsion is reduced to a minimum, thereby increasing the viscosity and durability of the emulsion.
However, in real-world applications, the degree of aggregation may be adjusted appropriately to achieve the desired performance due to differences in the needs of different applications.
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Acrylic emulsion needs to undergo polymerization reaction during the preparation process, and the reaction is complete to obtain high-quality acrylic emulsion. At the same time, the adequacy of the polymerization reaction also determines the performance and use effect of the acrylic emulsion. Therefore, when producing and using acrylic emulsions, care should be taken to ensure that the polymerization reaction is carried out adequately.
In the actual application process, it is also necessary to adjust and process the acrylic emulsion appropriately according to different needs to obtain the best use effect.
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Acrylic emulsion refers to a water-based acrylic resin emulsion, which is commonly used in coatings, adhesives, printing inks and other fields. Before use, the monomers of the emulsion need to be polymerized to make a polymer. However, in the actual production and use process, full polymerization is not necessary.
When the degree of aggregation reaches a certain level, sufficient performance can be obtained. At the same time, emulsions with a high solids content do not have to be fully polymerized, and the performance is guaranteed by a higher solids content.
In summary, acrylic emulsions need to polymerize monomers into polymers to get their desired properties, but complete polymerization is not necessary. In actual production and use, it can be adjusted according to the specific situation to meet the product requirements.
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Acrylic emulsion is one of the polymer emulsions, and the raw materials usually contain non-polymerized monomer acrylic acid, which needs to be polymerized through chemical reaction to produce polymer acrylic emulsion. Typically, acrylic emulsions need to be fully polymerized to have the desired physical and chemical properties. In the production process, we need to choose the right polymerization system, such as adding the right catalyst or inhibitor, etc., to achieve complete polymerization of acrylic emulsions.
Only after the polymerization is complete can the acrylic emulsion be guaranteed to have the properties it should have, such as stability and durability.
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Precautions*** Clean and dry the reaction system, maintain a suitable reaction temperature, and ensure the stability of the oxidant.
1. Ensure the cleanliness and dryness of the reaction system: the polymerization reaction needs to be carried out in a reactor without impurities, so the dilute acid treatment should be used to wash the reactor in advance. In addition, the reactor and instrumentation equipment must be completely dried before the reaction.
2. Maintain a suitable reaction temperature: The polymerization reaction needs to be carried out at a certain temperature, generally around 60. Temperatures that are too high may cause the reaction to be too fast, resulting in side reactions that can affect the polymerization quality.
3. Ensure the stability of oxidative concealment mask: benzoyl oxide is a commonly used oxidant, which can provide free radical reaction and promote polymerization reaction.
In the process of polystyrene emulsion polymerization, it is necessary to strictly control the reaction parameters and reaction conditions to avoid side reactions and ensure the stability of polymer quality.
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Summary. My dear. The role of ethanol added to the polymerization of acrylic emulsion is as follows:
It will destroy the dispersion performance of the polymer of the acrylic acid system in water, thereby causing the aggregation of emulsion particles, which will lead to demulsification and flocculation, so the addition of ethanol will not only not improve the temperature resistance of the acrylic system, but also destroy the structure of the acrylic system itself.
My dear. The role of ethanol added to the polymerization of acrylic acid emulsion is as follows: it will destroy the dispersion performance of the polymer of the acrylic acid system in water, thereby causing the aggregation of emulsion particles, which will lead to demulsification and flocculation.
Honey, it will dissolve if it heats up. 1.Ethanol and propylene esters are both polar molecules that are soluble according to the principle of similarity solubility.
Also ethanol can be sold to dissolve most organic matter. 2.Propylene is an organic substance, a molecular compound, insoluble in water, soluble in organic solvents, if you want it to be only soluble, it can be soluble in organic solvents such as carbon tetrachloride or benzene, but adding water will still stratify.
3.If it is required to add water without stratification, it can be mixed with ethanol (ethanol is miscible with water in any ratio and is an organic solvent) in the water, but note that both ethanol and benzene have strong volatility.
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Summary. Styrene acrylic resins are styrene-acrylic acid and its ester copolymers, which can dissolve or swell in water or form highly uniformly dispersed dispersions. It is usually characterized by low molecular weight (mn 2000 9000), narrow molecular weight distribution, and acid number 200.
Styrene acrylic resin is a very important class of water-based polymers, which usually have good wear resistance, chemical resistance, weather resistance and mechanical properties, and are widely used in inks, coatings, papermaking, sewage treatment, medicine, food, cosmetics and other fields. The traditional styrene acrylic resin is mainly a liquid product based on solution polymerization and emulsion polymerization, although it is easier to prepare a low molecular weight styrene acrylic resin by solution polymerization, but a large number of organic solvents will be used in the synthesis, these solvents are odorous, volatile, and toxic, and the subsequent solvent removal treatment is also required, which is time-consuming and labor-intensive, and the final resin sample still contains a certain amount of organic volatile components, which causes many inconveniences and product quality problems to downstream applications. The molecular weight of the products polymerized by emulsion is generally high, some even as high as millions, and the resin products prepared are also in a liquid state, which is generally sold and transported in a solvent-containing manner, which is very inconvenient for transportation, which not only limits the application range of customers, but also brings a certain burden to transportation.
I'm still a little confused, can you be more detailed?
Benzene luling propylene resin is a styrene-acrylic acid and its ester dismantling copolymer, the polymer can be dissolved or swollen in water, or form a highly homogeneously dispersed dispersion. It is often characterized by low molecular weight (mn 2000 9000), narrow molecular weight distribution, and acid number 200. Styrene acrylic resin is a very important class of water-based polymers, which usually have good wear resistance, chemical resistance, weather resistance and mechanical properties, and are widely used in inks, coatings, papermaking, sewage treatment, medicine, food, cosmetics and other fields.
The traditional styrene acrylic resin is mainly a liquid product based on solution polymerization and emulsion polymerization, although it is easier to prepare a low molecular weight styrene acrylic resin by solution polymerization, but a large number of organic solvents will be used in the synthesis, these solvents are odorous, volatile, and toxic, and the subsequent solvent removal treatment is also required, which is time-consuming and labor-intensive, and the final resin sample still contains a certain amount of organic volatile components, which causes many inconveniences and product quality problems to downstream applications. The molecular weight of the products polymerized by emulsion is generally high, some even as high as millions, and the resin products prepared are also in a liquid state, which is generally sold and transported in a solvent-containing manner, which is very inconvenient for transportation, which not only limits the application range of customers, but also brings a certain burden to transportation.
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Summary. Styrene emulsion polymerization can be stabilized by the following measures: increasing surfactants, controlling the polymerization temperature and pH value, adding stabilizers and preservatives, etc.
These measures can effectively control the size and distribution of particles in the emulsion, and prevent the emulsion from condensing or sedimenting, and maintain its stability.
Styrene emulsion polymerization can be stabilized by the following measures: increasing surfactants, controlling the polymerization temperature and pH value, adding stabilizers and preservatives, etc. These measures can effectively control the particle size and distribution in the emulsion, and prevent the emulsion from condensing or precipitation, and ensure the stability of the emulsion.
Can you add, I don't quite understand it.
Methods of stabilizing styrene emulsion polymerization include adding surfactants, controlling temperature, adjusting pH, adding stabilizers and preservatives. These measures can maintain the size of the particle size and the distribution of the limb, prevent the source of condensation and precipitation, and thus maintain stability.
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Polyacrylate emulsion (NBS copolymer) cement mortar, also known as: acrylic mortar, is an acrylate copolymer emulsion modified polymer cement mortar (abbreviation: NBS acrylic cement mortar), NBS acrylic is a cement-based polymer aqueous dispersion, also known as polymer cement mortar after adding cement mortar.
The mortar has excellent bonding, crack resistance, frost resistance, seepage resistance, anti-corrosion, chloride ion penetration resistance, aging resistance and corrosion resistance, and is suitable for anti-seepage, anti-corrosion protection and repair engineering of steel structures and reinforced concrete structures such as oceans, sluices, waterfalls, port projects, highways, bridges, metallurgy, chemical industry, industrial floors and civil buildings.
Oh, it's the ester that reacts polyester with acrylic.
Good afternoon, not recommended. PEGMA is an acrylate active monomer with photosensitizing functional groups, this monomer solvent is not suitable for long-term storage in both high and low temperature conditions, and the solubility of BHT will be seriously reduced at low temperatures, and may become a gel that cannot be recovered, please refer to it as appropriate. In the past, the UV that was mixed with PEGMA and HDDA and prepared to make benzophenone caused cross-linking turned out to be frozen into slimes in the refrigerator.
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