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Oxygen atoms. The electron shell structure is: 1s22s22p4, and the oxygen molecule is made up of two oxygen atoms. According to the valence bond theory, it was initially thought that the oxygen molecule was two oxygen atoms bonded together with a double bond, and its structural formula.
It can be expressed as follows:
Such a structural formula conformed to the principle of stable structure of Octopus, so it was recognized by the scientific community at that time.
In the forties of the twentieth century, paramagnetic resonance spectroscopy was discovered and confirmed to be caused by the presence of unpaired electrons in molecules or ions. Experiments with paramagnetic resonance spectroscopy have demonstrated that oxygen molecules are paramagnetic.
It was also proved that there are two unpaired electrons in the oxygen molecule. This experiment shows that the original structure of the oxygen molecule bound by double bonds is not realistic.
How does valence bond theory explain this fact? It acknowledges the existence of unpaired electrons and believes that two three-electron bonds are formed in the oxygen molecule, and the structural formula of the oxygen molecule is to be expressed as follows:
In the structural formula....Stands for three electronic bonds. How can a three-electron bond be formed between two oxygen atoms? According to Pauly's principle, an orbital can only hold two electrons with opposite spins, so a three-electron bond is formed from three electrons in two orbitals.
The energy released by forming a three-electron bond is only about half of the energy released by a single bond formed by one electron pair, so the three-electron bond is unstable. Three-electron bonds are electronegative only between two identical atoms.
Only atoms with very little difference can be formed. The theory of valence bonds does not have a clear explanation of how a three-electron bond is formed.
The theory of valence bonds is limited to the formation of chemical bonds.
The electrons are only within the region of two atoms that are connected. Later, the molecular orbital method, which focuses on the molecular structure as a whole, was developed and applied to the interpretation of the molecular structure of oxygen. The molecular orbital method holds that the electrons that form a chemical bond should move over an area spread throughout the molecule.
The oxygen molecule is made up of two oxygen atoms. Each oxygen atom has 8 electrons, and two oxygen atoms have 16 electrons. Of these 16 electrons, 4 electrons are in the k-layer and 12 electrons are in the l-layer.
It is mainly the electrons of the L shell that form molecular orbitals.
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An oxygen molecule is composed of two oxygen atoms, because the outermost shell of an oxygen atom has only 6 electrons, but the constituent molecule needs to reach a stable state (that is, the outermost shell reaches 8 electrons), so each oxygen atom keeps four electrons for its own use, and then no one takes out two electrons to share, so that each oxygen atom has 8 electrons in the outermost shell. The two pairs of electrons that are taken out to share are shared electron pairs, and because the center of the distance between the atoms and the center of gravity of the molecule coincide, they are non-acute bonds.
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is a non-polar bond in a covalent bond
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<> only van der Waals forces exist between oxygen molecules.
There is a non-polar covalent bond between two oxygen atoms.
Intermolecular forces.
Refers to an inert gas that exists between molecules or between molecules.
The forces between atoms, also known as van der Waals forces, are additive and belong to secondary bonds.
The ability of the same atom to attract the shared electron pairs is equal, the bonding electron pairs are evenly distributed between the two nuclei, and there is no bias towards any imitation fiber one atom, and the bonding atoms are not electrical. The distribution of the electric and quasi-charge in the molecule is symmetrical, and the positive charge center of gravity of the whole molecule coincides with the negative charge center of gravity, this molecule is called a non-polar molecule, this bond is called a non-polar covalent bond, and the non-polar bond exists in a single molecule.
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<> there is no double bond in the ground state O molecule, two three-electron bonds are formed in the oxygen molecule.
The molecular orbital electronic configuration of oxygen is.
There are unpaired single electrons in the orbitals, so the o molecule is the only one of all the diatomic gas molecules that has an even number of electrons and at the same time shows paramagnetism.
Two oxygen atoms undergo sp orbital hybridization, one single electron is filled into the sp hybrid orbital and bonded, and the other single electron is filled into the p orbital and bonded. Oxygen is an odd-electron molecule and is paramagnetic.
Under excitation, the two unpaired electrons of the oxygen molecule are paired, and the algebraic sum of the spin quantum number is s=0, 2s+1=1, which is called singlet oxygen.
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Oxygen (O2) is a colorless, odorless gas made up of two oxygen atoms. It has a molecular formula of O2 and a molecular weight of 32 g mol.
The two oxygen atoms in the molecular makeup of oxygen are bonded together in the form of covalent bonds. Each oxygen atom has six electrons but only two electrons are involved in the formation of a covalent bond, so each oxygen atom has four unpaired electrons that can react with other atoms or molecules. This is also the reason why oxygen is active and toxic.
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Oxygenate refers to the fact that in a chemical compound, a negative ion contains one or more oxygen atoms, usually ending with "-ate", such as sulfate SO4 2-, carbonate CO3 2-, etc. The bonding methods of these oxygenates mainly include ionic bonds and covalent bonds.
1.Ionic bonds: Ionic bonds are formed between the oxygenates and the cations.
In ionic bonding, the oxygen atom in the oxygenate group forms an electron transfer with the metal ion in the cation to form a positive ion and a negative ion, and the two ions attract each other through electrostatic action to form an ionic crystal.
2.Covalent bonds: The oxygen atom in the oxygenate group can form covalent bonds with other atoms, such as the hydroxyl group formed with the hydrogen atom, the carbonyl group formed with the carbon atom, etc.
In a covalent bond, the oxygen atom in the oxygenate group shares electron pairs with other atoms to form a covalent molecule. Dust Pond.
In conclusion, the way in which an oxygenate group is bonded depends mainly on the nature and number of other atoms in the compound in which it is located. In different compounds, the bonding formula of the oxytoic acid root may be different.
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Hello, oxygenate is a negative ion that is formed by an oxygenated acid molecule losing one or more hydrogen atoms and has a negative charge. Oxygenated acid molecules form strong oxidizing covalent or ionic bonds when bonding, resulting in the formation of oxygenate ions.
In the formation of oxynate ions, there may be several ways in which they form bonds. In general, oxygenate ions can form chemical bonds with atoms or ions in two ways:
1.Acid-base reaction.
In an acid-base reaction, the reaction of acid and base produces oxynate ions and water. At this time, the hydrogen ions in the acid are replaced by the hydroxide radical segments in the base, and a strong oxidizing ionic bond is formed.
2.Oxidation repentance reduction reaction.
In a redox reaction, the oxidation state of the oxygen element in the oxygenated acid molecule is changed to form an oxygenate ion. Redox reactions usually involve the transfer of electrons.
Overall, the most important characteristic of oxylate ions is that they have a negative charge, so they tend to form ionic bonds with cations that have a positive charge. According to different textbooks or professors, the description of bonding methods varies according to different textbooks or professors, but they usually emphasize the formation of covalent or ionic bonds.
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Summary. The bond energy is equal to the average of the stepwise dissociation energies, and if there is only one bond, such as HCL, the H-Cl bond energy is equal to the H-Cl dissociation energy.
However, if there are multiple bonds, the dissociation energies of the four C-H bonds are not equal numerically due to the change of the geometric configuration and electronic state of the product, such as CH4, the dissociation energies of the four C-H bonds are kj mol, and the c-h bond energy is equal to their average value of 411kj mol
So for the H2O molecule, its O-H bond energy should be equal to the average of the sum of the dissociation energies of the 2 O-Hs.
The bond energy of the oxygen molecule is equal to the dissociation energy.
Hello, I am happy to answer your questions, in the middle, please be patient, the specific answers are as follows:
Not true. The bond energy is equal to the average value of the stepwise dissociation energy, if there is only one root bond, such as HCL, the H-Cl bond energy is equal to the H-Cl dissociation energy slippery but if there are multiple bonds, due to the change of the geometric structure of the product, the Qi type and the electronic state, the dissociation energy of the four C-H bonds is not equal in value, such as CH4, the dissociation energy of the four C-H bonds is Kj mol, and the C-H bond energy is equal to their average value of 411Kj mol, so for H2O molecules, The O-H bond energy should be equal to the average of the sum of the dissociation energies of the 2 O-Hs.
I hope it can help you, if it helps you, please give a like, thank you. (・
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