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In analytical chemistry, the allowable relative error of [H] or OH calculations is generally within 5%. Using this as a criterion, the conditions used by various formulas can be calculated.
Taking the unary weak acid Hb as an example, let its concentration be cmol*L-1 and the dissociation constant is Ka.
Approximate formula [h+]=(-ka+ (ka2+4ka*c)) 2 The conditions for use are: kac 20kw
The simplest formula [h+] = (ka*c).
The conditions of use are: KAC 20KW C KA 400;
The approximate formula for calculating extremely dilute acid [H+]= ((Ka*C)+kW) is used under the following conditions: KAC 20 KW C KA 400;
The exact formula is [h+]3+ka[h+]2—(ka*c+kw)*[h+]—ka* kw=0
The conditions of use are: KAC 20KW C KA 400;
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The condition is that the C acid is relatively large, the H+ concentration is much greater than KW, and the C acid is much greater than Ka, the modified formula [H+] = (Ka*C acid) is used
pH = 1 2 (pka-LGC acid).
It would be too troublesome if you didn't fix the contract, so you should read the analysis textbook.
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This is only available in college textbooks, and you don't need to learn it in middle school, or there are materials for participating in high school chemistry competitions. I can only tell you so much, if you need to look up this information, I don't have any of it. Hope it helps.
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What formula ? What is the formula for calculating the ionization pH of a single weak acid?
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Monobasic weak acid. The formula for calculating pH: pH=(pka1+pka2) 1 2, a single weak acid refers to a molecule of a molecule of weak acid in an ideal state, which can be separated from a molecule of hydrogen ions before the electrolysis, and because it is a weak acid, it cannot be completely ionized, for example: fluorination changes to slow hydrogen.
Judge by PH: Shout Clear.
1. Measure the amount and concentration of the known substance Hb.
If the pH is greater than the pH of the same concentration of a strong acid, it means that Hb is a weak acid.
2. Take a certain volume of HB solution, measure its pH, and then dilute it 100 times, if the degree of pH increase is equal to 2 units, then HB is a strong acid; If the degree of pH increase is less than 2 units, Hb is a weak acid.
3. Take the HB solution, measure its pH, and then heat, if the PH becomes smaller, it means that HB is a weak acid (volatile and easily decomposed acids generally do not use this method).
4. Take the Hb solution, measure its pH, and then add a little Nab solid, if the pH becomes larger, it means that Hb is a weak acid.
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Monobasic strong acid. Exact: [H]c 4kw 2 Simplest Formula: [H]C
ph=-lgc
It is generally believed. When C 10 mol l. Available.
Monobasic weak acid. Exact: [h] ka [ha] kw minimalist: [h] kac
When kac 20kw and.
When C ka 500, i.e., C[H], then C-[H]C is available.
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Example: HA dissociation of CMOL L.
When equilibrium is reached, [a-].
H+], the equilibrium concentration of the weak acid Ha CH+]ka=[a-][H+] HA [H+]2 (CH+]) Because H+ is small, CH+]C
obtained: h+]=kac).
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C(Ag+)*C(Cl-)=4*10-10C(Ag+)=C(Cl-)=2*10-5mol L Solubility = (
g hydrochloric acid ionization of c(h+) = 10 -10
mol l ammonium chloride.
C(H+) = 10 -4 for ionization of water in China
Mol L ion concentration: C(Cl-)>C(NH4+)>C(H+)>C(OH-).
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