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See if the ingredients are usually weak acids and its conjugated bases.
Buffer solution refers to a mixed solution composed of weak acid and its salt, weak base and its salt, which can offset and reduce the pH of the solution to a certain extent.
to maintain the pH of the solution.
Relatively stable. 1. The pH value of the buffer is related to the ionization equilibrium constant ka of the acid and the concentration of salts and acids. The PKA value of weak acids is balanced, but when the ratio of acids and salts is different, different pH values are obtained.
When the acid and salt concentrations are equal, the pH of the solution is the same as the PKA.
2. When the concentration of acid and salt increases or decreases in equal proportions, the pH value of the solution remains unchanged.
3. When the acid and salt concentrations are equal, the buffering efficiency of the buffer is the highest, the greater the difference in the proportion, the lower the buffering efficiency, and the general effective buffer range of the buffer is pH=PKA1, POH=PKB 1.
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Measure the pH first, then drop a few drops of hydrochloric acid or sodium hydroxide and mix well, the pH does not change, and then continue to add, and after a certain amount, the pH will rise (add sodium hydroxide) or drop (add hydrochloric acid), which proves to be a buffer solution.
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The nature of the buffer solution is: a mixed solution composed of weak acid and its salt, weak base and its sodium salt, which can offset and alleviate the addition to a certain extentStrong acidsor a strong base against the solutionpHthe effect of keeping the solutionpHRelatively stable.
The buffer solution is inorganic chemistry.
and an important concept in analytical chemistry, a buffer solution is a solution that has the ability to maintain the relative stability of pH. The pH value does not change significantly within a certain range due to dilution or addition of a small amount of acid or base, and the buffer solution is based on the amount of conjugated acid-base pair and its substance.
Different with different pH and buffer capacity.
Characteristics of the buffer solution.
When a certain amount of acid and base is added to some solutions, it has the effect of hindering the pH change of the solution, which is called buffering, and such a solution is called buffer solution. Mixed solutions of weak acids and their salts (such as HAC and Naac), mixed solutions of weak bases and their salts (such as NH3H2O and NH4Cl) are buffer solutions.
The buffering effect of a buffer solution consisting of a weak acid HA and its salt Naa on the acid is due to the presence of a sufficient amount of alkali A- in the solution. When a certain amount of strong acid is added to this solution, the H ion is essentially consumed by the A-ion: so the pH of the solution is almost constant; When a certain amount of strong base is added.
The weak acid HA present in the solution depletes the OH- ion and hinders the change of pH.
The above internal clear beam capacity reference: Encyclopedia - buffer solution.
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1. The pH value of the buffer is related to the ionization equilibrium constant k of the acid and the concentration of salts and acids. When the concentration of acid and salt is equal, the pH value of the solution is the same as the PK value. When the concentration of acid and salt increases or decreases in equal proportions, the pH value of the solution does not change.
When the acid and salt concentrations are equal, the buffering efficiency of the buffer is high.
2. Add a small amount of strong acid or strong alkali to the buffer solution, and the pH value of the solution does not change much, but if the amount of acid and alkali is added, the buffer solution will lose its buffering effect. This shows that there is a limit to its buffering capacity.
3. The buffering capacity of the buffer solution is related to the concentration of the components that make up the buffer solution. and the composition of the buffer solution, which has a greater buffering capacity than the buffer solution of and. This is confirmed by calculations.
However, the concentration of the components of the buffer solution should not be too large, otherwise, the interaction between ions cannot be ignored.
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The reason why the buffer solution has a buffering effect: because the buffer solution is made ofWeak acidand its strong alkali salts, when acid is added, the weak acid is partially converted into a weak acid; When a base is added, the weak acid is partially converted into a weak salt。When an acid is encountered, the salt reacts with the acid to form a weak acid; When encountering a base, the weak acid reacts with the base to form salts, which keeps the pH of the solution basically unchanged.
If a strong base is added, but hydroxide ions in the solution.
There is very little change, and at the same time the concentration is larger, the relative change is small, and the ratio of the two is almost unchanged, so according to the formula, the concentration of hydronium ions changes very little. The same is true for the addition of weak acids. Since a small change in the large concentration base does not change the ratio change rate, the balance of hydrogen ion and hydroxide ion concentration in the system is maintained.
The significance of buffer solutions
Analytical tests were performed in complexation titration and spectrophotometry.
and many other reactions require the pH value of the solution.
Maintain a range to ensure the discoloration of the indicator and the chromogenic agent, etc., these conditions are achieved by adding a certain amount of buffer solution, so the buffer solution is a reagent that is often required in analytical tests.
The buffer solution is essential for maintaining the normal blood P h range in the human body. Among them, carbonic acid-sodium bicarbonate.
It is the most important buffering pair in plasma, and the buffering mechanism of this hail pair is closely related to the respiratory function of the lungs and the excretion and reabsorption functions of the kidneys. Carbon dioxide produced by normal human metabolism.
After entering the bloodstream, it combines with water to form carbonic acid, which is combined with bicarbonate in plasma.
Ion-conjugated acid-base is important for burying the sail, so the buffer solution is of great significance in medical testing.
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Buffer solution refers to a mixed solution composed of weak acid and its salt, weak base and its salt, which can offset and reduce the influence of external reinforcing acid or strong base on the pH of the solution to a certain extent, so as to keep the pH value of the solution relatively stable.
Acid-base buffered solutions are important factors in chemistry, biochemistry, and clinical medicine to maintain the direction of biochemical reactions. For an organism to sustain its life activities, its pH must be kept within a certain range, otherwise it will lead to death. Among the substances of biological **, the substances that participate in pH control or constitute a buffer system are proteins, organic acids and weak inorganic acids and their salts.
Citric acid (lemon and tomato), malic acid (apple and lettuce), oxalic acid (lettuce), and tartaric acid (grape and pineapple) are all substances that form a buffer system, and they generally work with phosphate to control pH. Cow's milk is a complex buffer system that contains carbon dioxide, proteins, phosphates, citrates, and other components.
In food processing, a buffer system is necessary to stabilize the pH of the system at the desired level. In the food industry, sodium salts of gluconic acid, acetic acid, citric acid, and phosphoric acid are often used to control pH and regulate sourness. Citrate is superior to phosphate in regulating the sourness, and its sourness appears more peaceful.
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Reasons why buffer solutions have a buffering effect:
Because the commonly used buffer solution is a combination of weak acid and its conjugate, when acid is added, the weak acid is partially converted into a weak acid; When a base is added, the weak acid is partially converted into a weak saltThe weak acid is not completely ionized in water, and the weak acid can be hydrolyzed in water, so the pH becomes less pure and the pH of the solution is basically unchanged.
The mixed solution composed of weak acid and its salt, weak base and its salt can offset and reduce the influence of external reinforcing acid or strong base on the pH of the solution to a certain extent, so as to keep the pH value of the solution relatively stable.
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Buffer solution (English: buffer solution) refers to ".Weak acidand the salts of the conjugated bases" or "the salts of the weak bases and their conjugated acids" are prepared to slow down the pH change when a certain amount of other substances are added.
The reason why two pairs of substances are used in the above definition is that the reaction can be buffered towards an acid or base at the same time, such as a mixed solution of acetic acid and sodium acetate.
It's a buffer solution. If hydrochloric acid is added, the pH will not drop too quickly, because hydrochloric acid will react with sodium acetate to form acetic acid. Conversely, if sodium hydroxide is added.
The pH does not increase too quickly because sodium hydroxide reacts with acetic acid to form sodium acetate.
in many chemical reactions.
, a buffer solution is used to make the pH of the solution.
Keep it constant. Buffer solutions are of great significance for the emergence and evolution of life, because most organisms can only grow within a certain pH range, for example, blood is a buffer solution.
Apply. Buffer solutions have many uses, such as the presence of dihydrogen phosphate-hydrogen phosphate and sodium carbonate-sodium bicarbonate in human blood.
Maintain the pH of the blood between to maintain the activity of the enzyme.
In industry, buffer solutions are often used to adjust the pH of dyes. The buffer solution can also be used to calibrate the pH meter.
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A buffer solution is a solution that greatly reduces the amplitude of pH fluctuations when a small amount of acid or base and water is added.
Composition of the buffer system:
1. Weak acid and its salts (such as HAC--- NAAC).
2. Weak alkali and its salt (.
3. Acid salts of multiple weak acids and their corresponding secondary salts (such as NaH2PO4--- Na2HPO4).
In biochemical research, it is often necessary to use buffer solutions to maintain the pH of the experimental system. The change of pH value of the solution system in the research work often directly affects the effectiveness of the research work. If the pH of the "Extraction Enzyme" system changes or changes drastically, the enzyme activity decreases or even loses completely.
Therefore, the preparation of buffer solutions is an indispensable and critical step.
Buffer solution is an important concept in inorganic chemistry and analytical chemistry, and buffer solution refers to a solution that can maintain the relative stability of pH. The pH value does not change significantly within a certain range due to dilution or addition of a small amount of acid or base, and the buffer solution has different pH value and buffer capacity according to the amount of conjugated acid-base pair and its substance.
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